ELECTROCATALYTIC OXIDATION OF METHANOL ON TERNARY COBALT ALLOYS

نویسندگان
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Facile Fabrication of Platinum-Cobalt Alloy Nanoparticles with Enhanced Electrocatalytic Activity for a Methanol Oxidation Reaction

Decreasing the cost associated with platinum-based catalysts along with improving their catalytic properties is a major challenge for commercial direct methanol fuel cells. In this work, a simple and facile strategy was developed for the more efficient preparation of multi-walled carbon nanotube (MWCNT) -supported Pt/CoPt composite nanoparticles (NPs) via solution plasma sputtering with subsequ...

متن کامل

Electrocatalytic Oxidation of Cyanide on Copper-doped Cobalt Oxide Electrodes

Copper and copper oxides are well-known excellent catalysts in several chemical processes, but their low mechanical and electrochemical stability restrict their direct utilization as electrodes in electrolytic processes. In this work, the incorporation of copper into cobalt oxide (CuxCo3-xO4) is presented as an excellent approach to obtain highly active and robust copper-based electrocatalysts....

متن کامل

Electrocatalytic oxidation of methanol on platinum modified polyaniline electrodes

Electrocatalytic oxidation of methanol on Pt modified polyaniline electrodes was investigated with the aim of developing highly active composite electrodes for direct methanol fuel cells. Cyclic voltammetry and chronoamperometry were used to evaluate the catalytic activity in sulfuric acid solutions containing methanol. Pt / polyaniline modified carbon electrodes showed higher catalytic activit...

متن کامل

Methanol oxidation over model cobalt catalysts: Influence of the cobalt oxidation state on the reactivity

X-ray photoelectron and absorption spectroscopies (XPS and XAS) combined with on-line mass spectrometry were applied under working catalytic conditions to investigate the methanol oxidation on cobalt. Two cobalt oxidation states (Co3O4 and CoO) were prepared and investigated as regards their influence on the catalytic activity and selectivity. In addition adsorbed species were monitored in the ...

متن کامل

Preparation of PtNi Nanoparticles for the Electrocatalytic Oxidation of Methanol

heating which are conducive to homogenous nucleation and a shorter crystallization time [14]-[16]; factors which are generally believed to be the prerequisite to the formation of monodisperse nanoparticles. Furthermore, microwave heating has also been found to increase reaction kinetics by one to two orders of magnitude [16]-[18]. Thus microwave assisted synthesis could pave way for the prepara...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Bulletin of the National Technical University "KhPI". Series: Chemistry, Chemical Technology and Ecology

سال: 2018

ISSN: 2079-0821

DOI: 10.20998/2079-0821.2018.39.12